Great stuff, thanks OP!
Personal advice from someone who bought both: The Martinis and Medicine collection is more expensive, but very much worth the extra.
They are on Amazon and often go on sale.
The Martinis and Medicine Complete Collection looks good because it has some extra reunion specials and such. I bought mine season by season as they were released in the late 90's. So I don't have this set.
The Martinis and Medicine Collection is also going for $99. It also contains the movie as well as two discs of bonus features including two reunion specials and a series retrospective episode of A&E's Biography. So if you're into that sort of thing, this might be the better deal. It also comes in an attractive box.
THAT BEING SAID, I own this collection and I will say that the packaging is awful if you plan to play these a lot. I highly recommend moving the discs to jewel cases or a CD wallet.