It's a 25 version
The velcro field isn't sown on (yet). It's currently tacked on with this stuff. I use it often and depending on the material you're sticking it to, it's fairly reliable without needing to stitch. Unless you're running the gear pretty hard
The water bottle pocket is the most intrusive outer pocket to the main cavity, but it's not bad. With a 32 oz. Nalgene though, I think it'd be a tight fit. It will definitely fit in the front lower compartment though, without taking up much of the main space. // [Some reference photos I just found on the TB forum about it, but I'm not sure if that's a Synapse 19 or a 25]
Not that you asked—but if I was looking to buy a TB backpack right now, I'd get the Synik 30, for the improvements and slightly extra space.